Halogen-bridged methylnaphthyl palladium dimers as versatile catalyst precursors in coupling reactions

Applicants must organize an interview with Prof. Gooßen before submitting their application. To schedule the interview, please email to sourav.manna@rub.de.

About the group and the topic

Our research is devoted to the development of straightforward catalytic “dream-reactions” as alternatives to inconvenient and hazardous multistep transformations. We are particularly interested in defining new strategies for the minimization of waste produced within a synthetic sequence by

• utilizing unusual substrate classes for catalytic cross-couplings
• activating inert molecules such as carbon dioxide
• regioselectivity functionalizing C−C, C−O or C−H bonds
• designing regio-and stereoselective catalytic addition reactions

The reaction portfolio includes homogeneous and heterogeneous catalysis, electrochemistry, and photochemistry. In the context of catalytic method development, we design novel catalysts and construct customized reactors as well as hard- and software tools for instrumental analysis. Our experimental work is supported by mechanistic investigations and quantum mechanical calculations, and complemented by organic syntheses that allow verifying the practical applicability of the new processes in the preparation of complex molecules such as pharmaceuticals.

What we expect from the students

• coursework or research experience in organic and inorganic chemistry
• experience in homogeneous catalysis is advantageous
• proficiency in techniques such as synthesis, purification, and characterization (e.g., NMR, IR, MS)
• strong problem-solving skills and attention to detail
• effective communication skills in English and/or German, both written and verbal
• constantly high motivation

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Paper related to the topic